Yesterday, we switched* our Subversion repository over to Mercurial and hosted it on Kiln. Check ‘er out: http://khanacademy.kilnhg.com
We switched for a number of reasons:

We’ve found an extremely talented high school developer in Omar Rizwan.
I could go on about improvements I know (hope) are waiting for us, but I want to stick to an honest description of the Khan Academy team’s experience, and it’s only been one day. Will let you know how it goes.
*Props to the Kiln team’s work on this part of the process . I started w/ an old machine that had neither Subversion nor Mercurial installed. Downloaded the Kiln Import Tool and ran it. It took me through installation, conversion, and upload seamlessly.